Aqueous‐phase ketonization of acetic acid over Zr/Mn mixed oxides
نویسندگان
چکیده
منابع مشابه
Theoretical study of the ketonization reaction mechanism of acetic acid over SiO2
The mechanism of ketonization of acetic acid over SiO2 was investigated by semiempirical quantum chemical AM1 method using the cluster approach. It has been found that the adjacent acid-base pair of the catalytic sites provokes dissociative adsorption of the acetic acid molecules resulting in the formation of surface carboxylate species. The adsorption process proceeds spontaneously. After bloc...
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ed from one carboxylate and a corresponding anionic radical was formed, while the surface Ce cations were partly RSC Adv., 2017, 7, 22017–22026 | 22023
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ژورنال
عنوان ژورنال: AIChE Journal
سال: 2017
ISSN: 0001-1541,1547-5905
DOI: 10.1002/aic.15687